Hi Reid,
I understand that you are using Office 365 Small Businesses account and you want to use SkyDrive with Office 365 account. However Office 365 doesn’t support this service.
For more questions about SkyDrive, you can post a new question in the SkyDrive forum.
Here is the link: http://answers.microsoft.com/en-us/windowslive/forum/skydrive?auth=1
Thanks,
Vivian Wang